1600-27-7

  • English Name: Mercury(II) Acetate
  • CAS Number: 1600-27-7
  • Molecular Formula: C₄H₆HgO₄
  • Molecular Weight: 318.68 g/mol

Physical Properties

  • Appearance: White crystalline powder or pale yellow powder with an acetic odor.
  • Density: 3.27 g/cm³.
  • Melting Point: 178-180°C.
  • Boiling Point: 117.1°C at 760 mmHg.
  • Solubility: Soluble in water, acetic acid, and dichloromethane; slightly soluble in ethanol; insoluble in benzene and hexane.
  • Sensitivity: Light-sensitive.

Chemical Properties

  • Stability: Stable but decomposes upon exposure to light.
  • Reactivity: Incompatible with strong oxidizing agents and bases.
  • Decomposition: Slowly hydrolyzes in water to form mercury(II) oxide (HgO) and acetic acid.

Applications

  1. Organic Synthesis: Used as a catalyst in organic reactions, such as hydromercuriation of alkenes and alkynes.
  2. Analytical Reagent: Used in chemical analysis.
  3. Pharmaceutical Industry: Used in the synthesis of certain pharmaceuticals.
  4. Gas Analysis: Used to absorb ethylene in gas analysis.

Safety Information

  • Toxicity: Highly toxic. Acute oral LD50 in rats: 40,900 μg/kg; in mice: 23,900 μg/kg.
  • Risk Phrases:
    • R26/27/28: Very toxic by inhalation, in contact with skin, and if swallowed.
    • R33: Danger of cumulative effects.
    • R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
  • Safety Phrases:
    • S13: Keep away from food, drink, and animal feeding stuffs.
    • S28: After contact with skin, wash immediately with plenty of soap and water.
    • S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
    • S60: This material and its container must be disposed of as hazardous waste.
    • S61: Avoid release to the environment. Refer to special instructions/Safety data sheets.

Handling and Storage

  • Store in a cool, dry place away from light. Keep containers tightly closed and avoid contact with strong oxidizing agents and bases.
  • Wear appropriate protective clothing, gloves, and eye protection when handling.

Environmental Concerns

  • Mercury compounds are highly toxic to aquatic life and should not be released into the environment.
  • Dispose of waste according to local regulations.

Packing and shipping