540-77-3

  • English Name: Perchloromethyl Mercaptan
  • CAS Number: 540-77-3
  • Molecular Formula: CCl₃SH
  • Molecular Weight: 158.57 g/mol

Physical Properties

  • Appearance: Colorless liquid.
  • Melting Point: -35°C.
  • Boiling Point: 112°C.
  • Density: 1.63 g/cm³ (at 25°C).
  • Solubility: Soluble in organic solvents like benzene, chloroform, and carbon tetrachloride; insoluble in water.
  • Odor: Characteristic, pungent odor.

Chemical Properties

  • Reactivity: Highly reactive; decomposes readily in the presence of bases or strong oxidizers.
  • Formation: Typically synthesized from chloroform (CHCl₃) and hydrogen sulfide (H₂S).
  • Decomposition: Releases toxic and corrosive gases (e.g., hydrogen chloride, sulfur dioxide) upon decomposition.

Uses

  • Chemical Synthesis: Used as a precursor for the synthesis of pharmaceuticals and other organic compounds.
  • Pesticides: Used in the production of certain pesticides.
  • Research: Used in chemical research for its unique reactivity.

Safety Information

  • Toxicity: Highly toxic; inhalation and ingestion can cause severe health effects.
  • Health Hazards: Causes severe irritation to eyes, skin, and mucous membranes. Inhalation can lead to respiratory distress and pulmonary edema.
  • Flammability: Not flammable but highly reactive with strong oxidizers and bases.
  • Risk Phrases:
    • R23/24/25: Toxic by inhalation, in contact with skin, and if swallowed.
    • R34: Causes burns.
    • R43: May cause sensitization by skin contact.
  • Safety Phrases:
    • S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
    • S36/37/39: Wear suitable protective clothing, gloves, and eye/face protection.
    • S45: In case of accident or if you feel unwell, seek medical advice immediately.

Handling and Storage

  • Store in a cool, dry place, away from strong oxidizers, bases, and moisture.
  • Use appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat.

Environmental Concerns

  • Toxic to aquatic life; avoid release into the environment.

First Aid Measures

  • Inhalation: Move to fresh air. If breathing is difficult, provide oxygen and seek medical attention.
  • Skin Contact: Wash with plenty of water and seek medical attention.
  • Eye Contact: Rinse with water for at least 15 minutes and seek medical attention.
  • Ingestion: Do not induce vomiting. Seek medical attention immediately.

Packing and shipping