7778-50-9

  • English Name: Potassium Dichromate
  • CAS Number: 7778-50-9
  • Molecular Formula: K₂Cr₂O₇
  • Molecular Weight: 294.185 g/mol

Physical Properties

  • Appearance: Bright red-orange crystalline solid.
  • Odor: Odorless.
  • Density: 2.676 g/cm³.
  • Melting Point: 398°C.
  • Boiling Point: 500°C (decomposes).
  • Solubility in Water:
    • 4.9 g/100 mL at 0°C.
    • 13 g/100 mL at 20°C.
    • 102 g/100 mL at 100°C.
  • Solubility in Other Solvents: Insoluble in alcohol and acetone.

Chemical Properties

  • Oxidizing Agent: Potassium dichromate is a strong oxidizing agent used in various chemical reactions.
  • Color Change:
    • In acidic conditions, it appears orange-red (Cr₂O₇²⁻).
    • In alkaline conditions, it turns yellow (CrO₄²⁻).
  • Thermal Decomposition:
    • Decomposes at high temperatures to form potassium chromate, chromium(III) oxide, and oxygen.
    • Reaction: 4K₂Cr₂O₇ → 4K₂CrO₄ + 2Cr₂O₃ + 3O₂.

Uses

  • Analytical Chemistry: Used as a reagent for detecting ferrous salts, iodides, and sulfides.
  • Leather Tanning: Used as a precursor for potassium chrome alum.
  • Photography: Used in photographic screen printing.
  • Glass Cleaning: Historically used as a cleaning agent for glassware (though discontinued due to safety concerns).
  • Medical Uses: Used externally as an antiseptic, caustic, and astringent.

Safety Information

  • Health Hazards:
    • Potassium dichromate is a known human carcinogen, particularly affecting the respiratory tract.
    • Causes severe irritation to skin and eyes; ingestion can lead to chemical burns.
  • Storage: Store in a cool, dry place, away from reducing agents and organic materials.
  • First Aid:
    • Skin Contact: Rinse with plenty of water.
    • Eye Contact: Rinse with water for at least 15 minutes.
    • Inhalation: Move to fresh air and seek medical attention.
    • Ingestion: Drink water and seek medical attention.

Environmental Information

  • Ecotoxicity: Highly toxic to aquatic life and may have long-term adverse effects.
  • Decomposition Products: Chromium(III) oxide, oxygen.

Transport Information

  • UN Number: 3288.
  • Hazard Class: 6.1 (Toxic substances).

Packing and shipping