67-66-3

  • English Name: Trichloromethane
  • CAS Number: 67-66-3.
  • Molecular Formula: CHCl₃.
  • Molecular Weight: 119.37.

Physical Properties

  • Appearance: Colorless, transparent liquid with a sweet odor.
  • Melting Point: -63.5°C.
  • Boiling Point: 61.12°C.
  • Density: 1.48 g/cm³.
  • Solubility: Insoluble in water, soluble in ethanol, ether, and benzene.
  • Refractive Index: High.

Chemical Properties

  • Stability: Stable under normal conditions but sensitive to light. Decomposes in the presence of light and air to form phosgene (a highly toxic gas) and hydrogen chloride.
  • Reactivity:
    • Reacts with strong bases to form dichlorocarbene.
    • Can be further chlorinated to form carbon tetrachloride.
    • Reacts with hydrogen fluoride to produce difluorochloromethane.

Uses

  • Medical Uses: Historically used as an anesthetic but is no longer recommended due to its hepatotoxicity.
  • Industrial Uses: Used as a solvent for fats, oils, resins, and waxes; also used in organic synthesis.
  • Other Uses: Formerly used in dry cleaning and as a refrigerant.

Safety Information

  • Toxicity: Highly toxic; inhalation, ingestion, and skin contact can cause severe health effects, including liver and kidney damage.
  • Health Hazards: Causes severe irritation to skin and eyes; inhalation may lead to central nervous system depression.
  • First Aid:
    • Skin Contact: Rinse thoroughly with soap and water.
    • Eye Contact: Rinse with plenty of water for at least 15 minutes.
    • Inhalation: Move to fresh air and seek medical attention.
    • Ingestion: Do not induce vomiting; seek medical attention.
  • Storage: Store in a cool, well-ventilated area, away from light and heat sources.

Environmental Information

  • Hazardous Decomposition Products: Phosgene and hydrogen chloride.
  • Ecotoxicity: Harmful to aquatic life.

Transport Information

  • UN Number: UN1888.
  • Hazard Class: 6.1 (Poisonous).

Regulatory Information

  • Classification: Suspected human carcinogen (GHS Category 2).
  • Occupational Exposure Limit: PC-TWA 20 mg/m³.

Packing and shipping